Recovered from the older tannerjc.net wiki snapshot dated January 23, 2016.

One of the things that has annoyed me with compiz compared to metacity as a window manager is the inability to easily set a keyboard shortcut to switch directly to a specific desktop. I set F1-F7 to go directly to desktops 1-7. In compiz you can’t do this easily. However it looks like it’s possible with CompizConfig Settings Manager

# yum install ccsm

You also need ‘wmctrl’

[jbrier@jb ~]$ wmctrl
wmctrl 1.07
Usage: wmctrl [OPTION]...
Actions:
  -m                   Show information about the window manager and
                       about the environment.
  -l                   List windows managed by the window manager.
  -d                   List desktops. The current desktop is marked
                       with an asterisk.
  -s DESK            Switch to the specified desktop.
  -a WIN             Activate the window by switching to its desktop and
                       raising it.
  -c WIN             Close the window gracefully.
  -R WIN             Move the window to the current desktop and
                       activate it.
  -r WIN -t DESK   Move the window to the specified desktop.
  -r WIN -e MVARG  Resize and move the window around the desktop.
                       The format of the MVARG argument is described below.
  -r WIN -b STARG  Change the state of the window. Using this option it's
                       possible for example to make the window maximized,
                       minimized or fullscreen. The format of the STARG
                       argument and list of possible states is given below.
  -r WIN -N STR    Set the name (long title) of the window.
  -r WIN -I STR    Set the icon name (short title) of the window.
  -r WIN -T STR    Set both the name and the icon name of the window.
  -k (on|off)          Activate or deactivate window manager's
                       showing the desktop mode. Many window managers
                       do not implement this mode.
  -o X,Y           Change the viewport for the current desktop.
                       The X and Y values are separated with a comma.
                       They define the top left corner of the viewport.
                       The window manager may ignore the request.
  -n NUM             Change number of desktops.
                       The window manager may ignore the request.
  -g W,H           Change geometry (common size) of all desktops.
                       The window manager may ignore the request.
  -h                   Print help.

Options:
  -i                   Interpret WIN as a numerical window ID.
  -p                   Include PIDs in the window list. Very few
                       X applications support this feature.
  -G                   Include geometry in the window list.
  -x                   Include WM_CLASS in the window list or
                       interpret WIN as the WM_CLASS name.
  -u                   Override auto-detection and force UTF-8 mode.
  -F                   Modifies the behavior of the window title matching
                       algorithm. It will match only the full window title
                       instead of a substring, when this option is used.
                       Furthermore it makes the matching case sensitive.
  -v                   Be verbose. Useful for debugging.
  -w WA              Use a workaround. The option may appear multiple
                       times. List of available workarounds is given below.

Arguments:
  WIN                This argument specifies the window. By default it's
                       interpreted as a string. The string is matched
                       against the window titles and the first matching
                       window is used. The matching isn't case sensitive
                       and the string may appear in any position
                       of the title.

                       The -i option may be used to interpret the argument
                       as a numerical window ID represented as a decimal
                       number. If it starts with 0x, then
                       it will be interpreted as a hexadecimal number.

                       The -x option may be used to interpret the argument
                       as a string, which is matched against the window's
                       class name (WM_CLASS property). Th first matching
                       window is used. The matching isn't case sensitive
                       and the string may appear in any position
                       of the class name. So it's recommended to  always use
                       the -F option in conjunction with the -x option.

                       The special string :SELECT: (without the quotes)
                       may be used to instruct wmctrl to let you select the
                       window by clicking on it.

                       The special string :ACTIVE: (without the quotes)
                       may be used to instruct wmctrl to use the currently
                       active window for the action.

  DESK               A desktop number. Desktops are counted from zero.

  MVARG              Specifies a change to the position and size
                       of the window. The format of the argument is:

                       G,X,Y,W,H

                       G: Gravity specified as a number. The numbers are
                          defined in the EWMH specification. The value of
                          zero is particularly useful, it means use the
                          default gravity of the window.
                       X,Y: Coordinates of new position of the window.
                       W,H: New width and height of the window.

                       The value of -1 may appear in place of
                       any of the X, Y, W and H properties
                       to left the property unchanged.

  STARG              Specifies a change to the state of the window
                       by the means of _NET_WM_STATE request.
                       This option allows two properties to be changed
                       simultaneously, specifically to allow both
                       horizontal and vertical maximization to be
                       altered together.

                       The format of the argument is:

                       (remove|add|toggle),PROP1[,PROP2]

                       The EWMH specification defines the
                       following properties:

                           modal, sticky, maximized_vert, maximized_horz,
                           shaded, skip_taskbar, skip_pager, hidden,
                           fullscreen, above, below

Workarounds:

  DESKTOP_TITLES_INVALID_UTF8      Print non-ASCII desktop titles correctly
                                   when using Window Maker.

The format of the window list:

  window ID desktop ID client machine window title

The format of the desktop list:

  desktop ID [-*] geometry viewport workarea title

Author, current maintainer: Tomas Styblo tripie@cpan.org
Released under the GNU General Public License.
Copyright (C) 2003
[jbrier@jb ~]$ wmctrl -s 2
[jbrier@jb ~]$ wmctrl -s Workspace 2
[jbrier@jb ~]$ wmctrl -s Workspace
 ^C
[jbrier@jb ~]$ wmctrl -s
wmctrl: option requires an argument -- 's'
[jbrier@jb ~]$ wmctrl -l
0x06200030  0 jb.usersys.redhat.com boten anna (dj micro spankin c by Basshunter
0x0140001e -1 jb.usersys.redhat.com x-nautilus-desktop
0x04a00156  0 jb.usersys.redhat.com About trianglebeats.com | TriangleBeats.com - Google Chrome
0x01000003 -1 jb.usersys.redhat.com Top Panel
0x01000028 -1 jb.usersys.redhat.com Bottom Panel
0x0640009d  0 jb.usersys.redhat.com *Unsaved Document 1 - gedit
0x06800003  0 jb.usersys.redhat.com jbrier@jb:~
0x05200003  0 jb.usersys.redhat.com jbrier@jb:~
0x06600003  0 jb.usersys.redhat.com jbrier@jb:/data/sxarchive/ereports/00367952/2010-11-08-dumps
0x01e00084  0 jb.usersys.redhat.com Inbox - jbrier@redhat.com zimbra - Mozilla Thunderbird
0x06000003  0 jb.usersys.redhat.com jbrier@jb:~/.weechat/logs
0x04c00003  0 jb.usersys.redhat.com [screen 0: weechat 0.3.2] weechat 0.3.2
0x05400003  0 jb.usersys.redhat.com jbrier@jb:~
0x04e00084  0 jb.usersys.redhat.com wmctrl - Wikipedia, the free encyclopedia - Mozilla Firefox
0x05600003  0 jb.usersys.redhat.com jbrier@jb:~
0x00e00003  0 jb.usersys.redhat.com CompizConfig Settings Manager
[jbrier@jb ~]$ wmctrl -d
0  * DG: 10240x1024  VP: 0,0  WA: 0,51 2560x973  Workspace 1
[jbrier@jb ~]$ wmctrl -l
0x06200030  0 jb.usersys.redhat.com boten anna (dj micro spankin c by Basshunter
0x0140001e -1 jb.usersys.redhat.com x-nautilus-desktop
0x04a00156  0 jb.usersys.redhat.com About trianglebeats.com | TriangleBeats.com - Google Chrome
0x01000003 -1 jb.usersys.redhat.com Top Panel
0x01000028 -1 jb.usersys.redhat.com Bottom Panel
0x0640009d  0 jb.usersys.redhat.com *Unsaved Document 1 - gedit
0x06800003  0 jb.usersys.redhat.com jbrier@jb:~
0x05200003  0 jb.usersys.redhat.com jbrier@jb:~
0x06600003  0 jb.usersys.redhat.com jbrier@jb:/data/sxarchive/ereports/00367952/2010-11-08-dumps
0x01e00084  0 jb.usersys.redhat.com Inbox - jbrier@redhat.com zimbra - Mozilla Thunderbird
0x06000003  0 jb.usersys.redhat.com jbrier@jb:~/.weechat/logs
0x04c00003  0 jb.usersys.redhat.com [screen 0: weechat 0.3.2] weechat 0.3.2
0x05400003  0 jb.usersys.redhat.com jbrier@jb:~
0x04e00084  0 jb.usersys.redhat.com wmctrl - Wikipedia, the free encyclopedia - Mozilla Firefox
0x05600003  0 jb.usersys.redhat.com jbrier@jb:~
0x00e00003  0 jb.usersys.redhat.com CompizConfig Settings Manager
[jbrier@jb ~]$ wmctrl -d
0  * DG: 10240x1024  VP: 2560,0  WA: 0,51 2560x973  Workspace 1
[jbrier@jb ~]$ wmctrl -n 2
[jbrier@jb ~]$ wmctrl -d
0  * DG: 10240x1024  VP: 0,0  WA: 0,51 2560x973  Workspace 1
1  - DG: 10240x1024  VP: 0,0  WA: 0,51 2560x973  Workspace 2
[jbrier@jb ~]$ wmctrl -n 4
[jbrier@jb ~]$ wmctrl -s 2
[jbrier@jb ~]$ wmctrl -s 1
[jbrier@jb ~]$ wmctrl -d
0  * DG: 2560x1024  VP: 0,0  WA: 0,51 2560x973  Workspace 1
1  - DG: 2560x1024  VP: N/A  WA: 0,51 2560x973  Workspace 2
2  - DG: 2560x1024  VP: N/A  WA: 0,51 2560x973  Workspace 3
3  - DG: 2560x1024  VP: N/A  WA: 0,51 2560x973  Workspace 4
4  - DG: 2560x1024  VP: N/A  WA: 0,51 2560x973  Workspace 5
5  - DG: 2560x1024  VP: N/A  WA: 0,51 2560x973  Workspace 6
6  - DG: 2560x1024  VP: N/A  WA: 0,51 2560x973  Workspace 7
[jbrier@jb ~]$ wmctrl -s 2

Then in CompizConfig Settings Manager (ccsm) go to General Commands set Key Bindings for all the Function keys, then in Commands set ‘wmctrl -s #’ (I think starting at 0) for all your equivalent Key Bindings/desktops.

I haven’t tested this yet but it should work.